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Battery shuts down at high temperatures; restarts when cool

11 January 2016

Stanford researchers have developed the first lithium-ion battery that shuts down before overheating, then restarts immediately when the temperature cools.

Stanford researchers have developed a thin polyethylene film that prevents a lithium-ion battery from overheating, then restarts the battery when it cools (photo: Zheng Chen, Stanford University)

The new technology could prevent the kind of fires that have prompted recalls and bans on a wide range of battery-powered devices, from recliners and computers to navigation systems and hoverboards.

"People have tried different strategies to solve the problem of accidental fires in lithium-ion batteries," says Stanford's Professor Zhenan Bao. "We've designed the first battery that can be shut down and revived over repeated heating and cooling cycles without compromising performance."

A typical lithium-ion battery consists of two electrodes and a liquid or gel electrolyte that carries charged particles between them. Puncturing, shorting or overcharging the battery generates heat. If the temperature reaches about 150 degrees Celsius, the electrolyte could catch fire and trigger an explosion.

Several techniques have been used to prevent battery fires, such as adding flame retardants to the electrolyte. In 2014, Stanford engineer Yi Cui created a 'smart' battery that provides ample warning before it gets too hot.

"Unfortunately, these techniques are irreversible, so the battery is no longer functional after it overheats," says Cui. "Clearly, in spite of the many efforts made thus far, battery safety remains an important concern and requires a new approach."

To address the problem Cui, Bao and postdoctoral scholar Zheng Chen turned to nanotechnology. Bao recently invented a wearable sensor to monitor human body temperature. The sensor is made of a plastic material embedded with tiny particles of nickel with nanoscale spikes protruding from their surface.

For the battery experiment, the researchers coated the spiky nickel particles with graphene and embedded the particles in a thin film of elastic polyethylene.

"We attached the polyethylene film to one of the battery electrodes so that an electric current could flow through it," says Chen. "To conduct electricity, the spiky particles have to physically touch one another. But during thermal expansion, polyethylene stretches. That causes the particles to spread apart, making the film non-conductive so that electricity can no longer flow through the battery."

When the researchers heated the battery 70 C, the polyethylene film quickly expanded like a balloon, causing the spiky particles to separate and the battery to shut down. But when the temperature dropped back down to 70 C, the polyethylene shrunk, the particles came back into contact, and the battery started generating electricity again.

"We can even tune the temperature higher or lower depending on how many particles we put in or what type of polymer materials we choose," sysd Bao. "For example, we might want the battery to shut down at 50 C or 100 C."

"Compared with previous approaches, our design provides a reliable, fast, reversible strategy that can achieve both high battery performance and improved safety," Cui said. "This strategy holds great promise for practical battery applications."

Bao and her colleagues describe the new battery in a study published in the January 11, 2016 issue of the journal, Nature Energy.


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