Graphene oxide 'paper' changes with strain
20 January 2016
US researchers have found that random molecules scattered within layers of otherwise pristine graphene affect how the layers interact with each other under strain.
The same slip-and-stick mechanism that leads to earthquakes is at work on the molecular level in nanoscale materials, where it determines the shear plasticity of the materials, according to scientists at Rice University and the State University of Campinas, Brazil.
Plasticity is the ability of a material to permanently deform when strained. Rice University researchers, working on a range of projects, including flexible electronics, determined to find out how graphene oxide 'paper' would handle shear strain, in which the sheets are pulled by the ends.
"We want to build three-dimensional structures from two-dimensional materials, so this kind of study is useful," says Rice post-doctoral research associate, Chandra Sekhar Tiwary. "These structures could be a thermal substrate for electronic devices, they could be filters, they could be sensors or they could be biomedical devices. But if we're going to use a material, we need to understand how it behaves."
The graphene oxide paper they tested was a stack of sheets that lay atop each other like pancakes. Oxygen molecules 'functionalised' the surfaces, adding roughness to the otherwise atom-thick sheets.
In experiments and computer models, the team found that with gentle, slow stress, the oxides would indeed catch, causing the paper to take on a corrugated form where layers pulled apart. But a higher strain rate makes the material brittle.
"The simulation performed by our collaborators in Brazil provides insight and confirms that if you pull it very fast, the layers don't interact, and only one layer comes out," Tiwary says.
"After this study, we now know there are some functional groups that are useful and some that are not. With this understanding we can choose the functional groups to make better structures at the molecular level."
An article describing this work is published in the American Chemical Society journal, Nano Letters.