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Scientists bridge different materials by design

05 February 2016

University of Liverpool scientists have shown that it is possible to design and construct interfaces between materials with different structures by bridging them.

In this analogy, it is possible to construct a flexible block, which will fit with both materials and bridge the gap between them, like the blue block bridging the gap between the red and green ones (image: University of Liverpool)

It is usually possible to make well-controlled interfaces when two materials have similar crystal structures, yet the ability to combine materials with different crystal structures has lacked the accurate design rules that increasingly exists in other areas of materials chemistry.

The design and formation of an atomic-scale bridge between different materials will lead to new and improved physical properties, opening the path to new information technology and energy science applications amongst a myriad of science and engineering possibilities - for example, atoms could move faster at the interface between the materials, enabling better batteries and fuel cells.

Many devices - for example, a transistor or blue LED - rely on the creation of very clean, well-ordered interfaces between different materials to work.

"When we try to fit materials together at the atomic scale, we are used to using the sizes of the atoms to decide which combinations of materials will 'work - that will produce a continuous well-ordered interface," says Liverpool materials chemist, Professor Matthew Rosseinsky.

"The project team added in consideration of the chemical bonding around the atoms involved, as well as their sizes, as a key design step. This allowed the selection of two materials with different crystal structures yet with sufficient chemical flexibility to grow in a completely ordered manner throughout the interface between them.

"This was achieved by the formation of a unique ordered structure at the interface which did not correspond to either material but contained features of both of them: an atomic-scale bridge."

An article describing the work is published in the journal, Nature Chemistry. Researchers at the University of Antwerp were also involved in this work.


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