'Ready-to-go' battery electrode with glass-ceramic
31 March 2016
A paperlike battery electrode developed by a Kansas State University engineer may improve tools for space exploration or unmanned aerial vehicles.
Gurpreet Singh, associate professor of mechanical and nuclear engineering, and his research team created the battery electrode using silicon oxycarbide-glass and graphene.
The battery electrode has all the right characteristics. It is more than ten percent lighter than other battery electrodes. It has close to 100 percent cycling efficiency for more than 1,000 charge discharge cycles. It is made of low-cost materials that are by-products of the silicone industry and it functions at temperatures as low as -15°C, which gives it numerous aerial and space applications.
Singh's research team has been exploring new material combinations for batteries and electrode design. It has been difficult to incorporate graphene and silicon into practical batteries because of challenges that arise at high mass loadings — such as low capacity per volume, poor cycling efficiency and chemical-mechanical instability.
Singh's team has addressed these challenges by manufacturing a self-supporting and ready-to-go electrode that consists of a glassy ceramic called silicon oxycarbide sandwiched between large platelets of chemically modified graphene, or CMG. The electrode has a high capacity of approximately 400 miliampere-hours per cubic centimetre that is derived from silicon oxycarbide. The paperlike design is made of 20 percent chemically modified graphene platelets.
"The paper like design is markedly different from the electrodes used in present day batteries because it eliminates the metal foil support and polymeric glue — both of which do not contribute toward capacity of the battery," Singh said.
"The rechargeable batteries from silicon-glass and graphene electrodes may also be suitable for unmanned aerial vehicles flying at high altitudes, or maybe even space applications," Singh said.
The silicon oxycarbide material itself is quite special, Singh said. It is prepared by heating a liquid resin to the point where it decomposes and transforms into sharp glasslike particles. The silicon, carbon and oxygen atoms get rearranged into random 3D structure and any excess carbon precipitates out into cellular regions. Such an open 3D structure creates large sites for reversible lithium storage and smooth channels for lithium-ion transportation. This structure and mechanism of lithium storage is different than crystalline silicon electrodes. Silicon oxycarbide electrodes are expected to be low cost because the raw material — liquid resin — is a by-product of the silicone industry.
Moving forward, Singh and his team want to address practical challenges. Singh's goal is to produce this electrode material at even larger dimensions. The team also would like to perform mechanical bending tests to see how they affect performance parameters.
"Ultimately, we would like to work with industry to explore production of lithium-ion battery full-cells," Singh said. "Silicon oxycarbide can also be prepared by 3D printing, which is another area of interest to us."
The research appears in Nature Communications article "Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries."
For more information visit the Kansas State University website.