Upsize nanostructures into 3D printed materials
20 July 2016
Researchers describe a process to create lightweight, strong and super-elastic 3D printed metallic nanostructured materials with unprecedented scalability.
For years, scientists and engineers have synthesised materials at the nanoscale level to take advantage of their mechanical, optical, and energy properties, but efforts to scale these materials to larger sizes have resulted in diminished performance and structural integrity.
Now, researchers led by Xiaoyu “Rayne” Zheng, an assistant professor of mechanical engineering at Virginia Tech, have published a study in the journal Nature Materials that describes a new process to create lightweight, strong, and super-elastic 3D printed metallic nanostructured materials with unprecedented scalability, a full seven orders of magnitude control of arbitrary 3D architectures.
Strikingly, these multiscale metallic materials have displayed super elasticity because of their designed hierarchical 3D architectural arrangement and nanoscale hollow tubes, resulting in more than a 400 percent increase of tensile elasticity over conventional lightweight metals and ceramic foams.
The approach, which produces multiple levels of 3D hierarchical lattices with nanoscale features, could be useful anywhere there’s a need for a combination of stiffness, strength, low weight, and high flexibility - such as in structures to be deployed in space, flexible armours, lightweight vehicles, and batteries, opening the door for applications in aerospace, military, and automotive industries.
Natural materials, such as trabecular bone and the toes of geckos, have evolved with multiple levels of 3D architectures, spanning from the nanoscale to the macroscale. Human-made materials have yet to achieve this delicate control of structural features.
“Creating 3D hierarchical micro features across the entire seven orders of magnitude in structural bandwidth in products is unprecedented,” said Zheng, the lead author of the study and the research team leader. “Assembling nanoscale features into billets of materials through multi-levelled 3D architectures, you begin to see a variety of programmed mechanical properties, such as minimal weight, maximum strength, and super elasticity at centimetre scales.”
The process Zheng and his collaborators use to create the material is an innovation in a digital light 3D printing technique that overcomes current tradeoffs between high resolution and build volume, a major limitation in scalability of current 3D printed microlattices and nanolattices.
Related materials that can be produced at the nanoscale, such as graphene sheets, can be 100 times stronger than steel, but trying to upsize these materials in three dimensions degrades their strength eight orders of magnitude — in other words, they become 100 million times less strong.
“The increased elasticity and flexibility obtained through the new process and design come without incorporating soft polymers, thereby making the metallic materials suitable as flexible sensors and electronics in harsh environments, where chemical and temperature resistance are required,” Zheng said.
This multi-levelled hierarchical lattice also means more surface area is available to collect photons' energies, as they can enter the structure from all directions and be collected not just on the surface, like traditional photovoltaic panels, but also inside the lattice structure. One of the great opportunities this study creates is the ability to produce multi-functional inorganic materials, such as metals and ceramics, to explore photonic and energy-harvesting properties in these new materials.
Besides Zheng, team members include Virginia Tech graduate research students Huachen Cui and Da Chen from Zheng’s group, and colleagues from Lawrence Livermore National Laboratory. The research was conducted under Department of Energy Lawrence Livermore Laboratory-directed research support with additional support from Virginia Tech, the SCHEV Fund from the commonwealth of Virginia, and the Defence Advanced Research Projects Agency.