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'Remarkable' spray-on coating combines carbon nanotubes with ceramic

18 April 2013

Researchers have demonstrated a spray-on mixture of carbon nanotubes and ceramic that has unprecedented ability to resist damage while absorbing laser light.

A micrograph of one strand of the new spray-on super-nanotube composite, falsely coloured for clarity (image: Kansas State University)

The work was carries out by the US National Institute of Standards and Technology (NIST), and Kansas State University .

Coatings that absorb as much of the energy of high-powered lasers as possible without breaking down are essential for optical power detectors that measure the output of such lasers, which are used, for example, in military equipment for defusing unexploded mines.

"It really is remarkable material," says NIST's John Lehman. "It's a way to make super-nanotubes. It has the optical, thermal and electrical properties of nanotubes with the robustness of the high-temperature ceramic."

The composite was developed by Kansas State. NIST researchers suggested using toluene to uniformly coat individual nanotubes with a ceramic shell. They also performed damage studies showing how well the composite tolerates exposure to laser light.

The new composite consists of multi-wall carbon nanotubes and a ceramic made of silicon, boron, carbon and nitrogen. Boron boosts the temperature at which the material breaks down.

The nanotubes were dispersed in toluene, to which a clear liquid polymer containing boron was added drop by drop, and the mixture was heated to 1,100 degrees C. The resulting composite was then crushed into a fine powder, dispersed in toluene, and sprayed in a thin coat on copper surfaces. Researchers baked the test specimens and then exposed them to a far-infrared laser beam of the type used to cut hard materials.

Analysis revealed that the coating absorbed 97.5 percent of the light and tolerated 15kW of laser power per square centimeter for 10 seconds. This is about 50 percent higher damage tolerance than other research groups have reported for similar coatings tested with the same wavelength of light.

The nanotubes and graphene-like carbon absorb light uniformly and transmit heat well, while the oxidation-resistant ceramic boosts damage resistance. The spray-on material also adheres well to the copper surface. As an added bonus, the composite can be produced easily in large quantities.

After light exposure, the coatings were analysed using several different techniques. Electron microscopy revealed no major destruction such as burning or deformation. Other tests showed the coating to be adaptable, with the ceramic shell partially oxidising into a stable layer of silicon dioxide (quartz).


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