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A sulphur and nanostuctured carbon cathode could slash cost of li-ion batteries

17 March 2013

A new lithium-ion battery cathode technology could provide double the energy storage, and at lower cost, than the batteries currently in use.

A 'forest' of carbon nanotubes. Image: Shutterstock
A 'forest' of carbon nanotubes. Image: Shutterstock

Batteries used in applications such as handheld electronics, electric vehicles, aerospace and defence, are typically based on lithium and a metal oxide, such as cobalt, manganese or nickel.

Researchers from the University of Cambridge have developed a composite of sulphur and nanostructured carbon for use as a battery cathode with much higher energy storage at much lower cost than conventional materials.

The raw cathode materials are the single largest material cost in battery production, representing between 35 and 40 percent of total costs.

The global lithium-ion battery market is expected to expand to $54bn by 2020, up from $11.8bn in 2010, driven primarily by demand from the consumer electronics and electric vehicle sectors.

Dr Can Zhang, of the Department of Engineering, is one of the developers of the material. He said: "Using sulphur instead of the materials currently used in lithium-ion batteries could substantially reduce production costs, as sulphur is a fraction of the cost of other materials.

"Additionally, compared with conventional lithium-ion batteries, the carbon-sulphur electrodes achieve double the energy density per unit of weight."

The carbon-sulphur electrodes are produced by growing a "forest" of high-quality carbon nanotubes (CNTs) on a layer of metal foam. The CNT forest provides excellent electrical conductivity, and acts as a three-dimensional scaffold into which the sulphur is injected in order to form the cathode.

The sulphur is trapped within the scaffold in the form of small particles which store electrons. The pore structure of the metal foam, combined with the dense vertical packing of CNTs, provides a labyrinth with a large surface area for the retention of electrode material.

Despite their higher density and lower costs, the commercial development of lithium-sulphur batteries has been largely plagued by short cycle life, typically below 80 charge-discharge cycles. In comparison, a conventional lithium-ion battery will usually achieve 500 charge-discharge cycles. The CNT-sulphur composite significantly enhances the cycle performance of lithium-sulphur batteries, retaining 80 percent capacity after over 250 full charge-discharge cycles.

The work is the result of a collaboration between the groups of Professor John Robertson of the Department of Engineering and Dr Vasant Kumar of the Department of Materials Science and Metallurgy.

Dr Zhang, a postdoctoral researcher in Professor Robertson's group, has formed CamBattery to commercialise the technology, along with PhD students Bingan Chen, Kai Xi and Wentao He. The company won Technology Start-up of the Year at the 2012 Cambridge University Entrepreneurs competition.

Over the next two years, the team intends to build the first roll-to-roll machine to continuously produce the cathode material, and sell the product to major battery manufacturers. While the number of charge-discharge cycles achieved by lithium-sulphur batteries is not yet high enough for CamBattery to enter the consumer electronics market, applications in aerospace and defence are strong possibilities.

"For aerospace and defence applications, energy storage takes precedence over life cycle," said Dr Zhang. "However, we will continue working at getting the number of life cycles high enough for consumer electronics and electric vehicles."

This story originated here.

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